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Medium
Urethane Reducer
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DATE:3/05/02
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ABPA
81 Medium Urethane Reducer
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MATERIAL
SAFETY DATA SHEET
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| THIS MSDS COMPLIES WITH 29 CFR 1910.1200 ( HAZARD COMMUNICATION STANDARD) | ||
| IMPORTANT: Read this MSDS before handling and disposing of this product. | ||
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Pass this information on to employees, customers, & users of this product. | |
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SECTION
1. CHEMICAL PRODUCTS & COMPANY IDENTIFICATION
/ HAZARD RATINGS
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| PRODUCT IDENTITY: | Blend #9820 ABA 81 Medium Urethane Reducer |
HEALTH RATINGS: |
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| COMPANY IDENTITY: | Keystone Automotive Industries |
HEALTH (NFPA) = |
2 | |
| COMPANY ADDRESS: | 700 East Bonita Anenue | HEALTH (HMIS) = | 2 | |
| Pomona, CA 91767 | FLAMMABILITY = |
3 |
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| COMPANY PHONE: | 1-800-772-5557 | REACTIVITY = | 0 | |
| CHEMTREC PHONE: | 1-800-424-9300 | |||
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SECTION
2. INGREDIENT & REGULATORY INFORMATION
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| All components of this product are on the TSCA list. | |
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SARA Title III Section 313 Supplier Notification |
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| This product contains the indicated <*> toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning & Community Right-To-Know Act of 1986 & of 40 CFR 372. This information must be included in all MSDSs that are copied and distributed for this material. | |
| SARA TITLE III INGREDIENTS | CAS# | WT. % | (REG.SECTION) | RQ (LBS) | |
| Acetone | 67-64-1 | Not Appl. | (311, 312) |
5000
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| Light Aliphatic Solvent Naphtha | *64742-89-8 | Not Appl. | (311, 312) |
None
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| Propylene Glycol Methyl Ether Acetate | 108-65-6 | Not Appl. | (311, 312) | None | |
| Isobutyl Acetate | 110-19-0 | Not Appl. | (311, 312) |
None
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| *Toluene | 108-88-3 | 10 | (311, 312, 313, RCRA) | 1000 | |
| n-Butyl Acetate | 123-86-4 | Not Appl. | (311, 312) | 5000 | |
| *Mixed Xylenes | 1330-20-7 | < 5 | (311, 312, 313, RCRA) | 100 | |
| *Ethylbenzene | 67-56-1 | < 5 | (311, 312, 313, RCRA) |
1000
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| SARA SECTION 311/312 HAZARDS: Acute Health, Chronic Health, Fire | |||||
| MATERIAL |
CAS#
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TWA
(OSHA)
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TLV
(ACGIH)
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HAP
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| Acetone | 67-64-1 | 1000 ppm | 500 ppm | No | |
| Light Aliphatic Solvent Naphtha | *64742-89-8 |
500
ppm
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300 ppm |
No
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| Propylene Glycol Methyl Ether Acetate | 108-65-6 | None Known | 100 ppm | No | |
| Isobutyl Acetate | 110-19-0 | 150 ppm | 150 ppm | No | |
| *Toluene | 108-88-3 | 200 ppm | 50 ppm | Yes | |
| n-Butyl Acetate | 123-86-4 | 150 ppm | 150 ppm | No | |
| *Mixed Xylenes | 1330-20-7 | 100 ppm | 100 ppm | Yes | |
| *Ethylbenzene | 67-56-1 | 100 ppm | 100 ppm | Yes | |
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In addition to EPA Hazardous Air pollutants showing 'Yes' under "HAP" above, using manufacturers' data, based on EPA Method 311, the following EPA Hazardous Air Pollutants may be present in trace amounts (less than 0.1%) = Benzene, Cumene |
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| MATERIAL | CAS# | CEILING | STEL (OSHA/ACGIH) | |
| Acetone | 67-64-1 | None Known | 750 ppm | |
| Light Aliphatic Solvent Naphtha | *64742-89-8 | None Known | 5.3E3 ppm | |
| n-Butyl Acetate | 123-86-4 | None Known | 200 ppm | |
| *Mixed Xylenes | 1330-20-7 | None Known | 150 ppm | |
| *Ethylbenzene | 67-56-1 | None Known | 125 ppm | |
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CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the state of California to cause cancer & reproductive toxicity: Benzene, Toluene |
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| IF > 2381 POUNDS OF THIS PRODUCT IS IN ONE CONTAINER THE 'RQ' IS EXCEEDED. | |||
| DOT SHIPPING NAME: Paint Related Material, 3, UN1263, PG II | |||
| DRUM LABEL:(FLAMMABLE LIQUID) | |||
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SECTION
3. HAZARDS IDENTIFICATION
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| MATERIAL | CAS# | LOWEST KNOW LETHAL DOSE DATA | |
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LOWEST KNOWN LD50 (ORAL) |
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| *Toluene | 108-88-3 | 3000.0 mg/kg (Rats) | |
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THRESHOLD LIMIT VALUE: 175 ppm (Evaporated Blend) |
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CONTAINS: ACETONE, LIGHT ALIPHATIC SOLVENT NAPHTHA, PROPYLENE GLYCOL ETHER ACETATE, |
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| ISOBUTYL ACETATE, TOLUENE, N-BUTYL ACETATE, MIXED XYLENES, ETHYLBENZENE | |
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DANGER!! |
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EXTREMELY
FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
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ACUTE
HAZARDS
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| EYE & SKIN CONTACT: | |
| Primary irritation to skin, defatting, dermatitis. | |
| Absorption thru skin increases exposure. | |
| Primary irritation to eyes, redness, tearing, blurred vision. | |
| Liquid can cause eye irritation. Wash thoroughly after handling. | |
| INHALATION: | |
| Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system depression. Vapor harmful. | |
| Breathing vapor can cause irritation. | |
| Acute overexposure can cause damage to kidneys, blood, nerves, liver & lungs. | |
| SWALLOWING: | |
| Harmful or fatal if swallowed. | |
| Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea. | |
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SUBCHRONIC
HAZARDS / CONDITIONS AGGRAVATED
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| CONDITIONS AGGRAVATED | ||
| Chronic overexposure can cause damage to kidneys, blood, nerves, liver, & lungs. | ||
| Persons with severe skin, liver or kidney problems should avoid use. | ||
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CHRONIC
HAZARDS
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| CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS: | ||
| Due to metabolic differences, the results are not relevant in humans. | ||
| This product may contain less than 52 ppm of Benzene. | ||
| Not considered hazardous in such low concentrations. | ||
| Absorption through skin may be harmful. Studies with laboratory animals indicate this product can cause damage to fetus. | ||
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SECTION
4. FIRST AID MEASURES PROCEDURES
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| EYE CONTACT: | ||
| For eyes, flush with plenty of water for 15 minutes & get medical attention. | ||
| SKIN CONTACT: | ||
| In case of contact with skin immediately remove contaminated clothing. | ||
| Wash thoroughly with soap & water. Wash contaminated clothing before reuse. | ||
| (Discard contaminated shoes) | ||
| INHALATION: | ||
| After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped give | ||
| artificial respiration. CALL A PHYSICIAN IMMEDIATELY! | ||
| SWALLOWING: | ||
| If swallowed, CALL A PHYSICIAN IMMEDIATELY! Do NOT induce vomiting. | ||
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Have patient lie down & keep warm. Vomiting may lead to pneumonitis, which may be fatal |
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SECTION
5. FIRE FIGHTING MEASURES
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| AUTO IGNITION TEMPERATURE: 290 C / 555 F (Lowest Component) | ||
| LOWER FLAMMABLE LIMIT IN AIR (% by vol): 1.9 | ||
| FLASH POINT (TEST METHOD): -16 C / 2 F (TCC) (Lowest Component) | ||
| FLAMMABILITY CLASSIFICATION: Class I B | ||
| EXTINGUISHING MEDIA | ||
| NFPA Class B extinguishers (Carbon Dioxide or foam) for Class I B liquid fires. | ||
| SPECIAL FIRE FIGHTING PROCEDURES | ||
| Water spray may be ineffective on fire but can protect fire-fighters & cool closed containers. Use fog nozzles if water is used. | ||
| Do not enter confined fire-space without full bunker gear. (Helmet with face shield, bunker coats, gloves & rubber boots). | ||
| Use NIOSH approved positive-pressure self-contained breathing apparatus. | ||
| UNUSUAL EXPLOSION AND FIRE PROCEDURES | ||
| EXTREMELY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE | ||
| Keep container tightly closed. | ||
| Isolate from oxidizers, heat, sparks, electric equipment & open flame. | ||
| Closed containers may explode if exposed to extreme heat. | ||
| Applying to hot surfaces requires special precautions. | ||
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Empty container very hazardous! Continue all label precautions |
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SECTION
6. ACCIDENTAL RELEASE MEASURES
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| SPILL OR LEAK PROCEDURES | |
| Stop spill at source. Dike area & contain. Clean up remainder with absorbent materials. Mop up & dispose of. Persons | |
| without proper protection should be kept from area until cleaned up. | |
| WASTE DISPOSAL METHOD | |
| Recycle or dispose of observing local, state & Federal health, safety & pollution laws. If questions exist, contact the | |
| appropriate agencies. | |
| OTHER PRECAUTIONS | |
| Vapors may ignite explosively & spread long distances. Prevent vapor buildup. Put out pilot lights & turn off heaters, electric equipment & other ignition sources during use & until all vapors are gone. | |
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SECTION
7. HANDLING AND STORAGE
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| HANDLING | |
| Isolate from oxidizers, heat, sparks, electric equipment & open flame. | |
| Use only with adequate ventilation. Avoid breathing of vapor or spray mist. | |
| Avoid contact with skin & eyes. | |
| Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. | |
| Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse. | |
| Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, saw, drill, braze, or weld. Empty container | |
| very hazardous! Continue all label precautions! | |
| STORAGE | |
| Vapors may ignite explosively & spread long distances. Prevent vapor buildup. | |
| Put out pilot lights & turn off heaters, electric equipment & other ignition sources during use & until all | |
| vapors are gone. | |
| Do not store above 49 C / 120 F. Store large amounts in structures made for OSHA Class I B liquids. | |
| Keep container tightly closed & upright when not in use to prevent leakage. | |
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SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| EXPOSURE CONTROLS | ||
| Ventilate to keep vapors of this material below 90 ppm. If over TLV, in accordance with 29 CFR 1910.134, use NIOSH approved positive-pressure self-contained breathing apparatus. Consult Safety Equipment Supplier. Use explosion-proof equipment. | ||
| VENTILATION | ||
| LOCAL EXHAUST | = Necessary | |
| MECHANICAL (GENERAL) | = Acceptable | |
| SPECIAL | = None | |
| OTHER | = None | |
| PERSONAL PROTECTIONS: | ||
| Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. | ||
| Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse. | ||
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SECTION
9. PHYSICAL DATA
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| APPEARANCE: | Liquid, Water-White | |
| ODOR: | Ketone | |
| BOILING RANGE: | 56 102 147 C / 133 216 298 F | |
| GRAVITY @ 60 F: | ||
| API: | 39.3 | |
| SPECIFIC GRAVITY (Water = 1): | .829 | |
| POUNDS / GALLON: | 6.903 | |
| VOC'S (>0.44 LBS / SQ IN): | 84.9 Vol. % / 704.0 g/L / 5.863 Lbs/Gal | |
| TOTAL VOCıS (TVOC): | 100.0 Vol. % / 828.7 g/L / 6.902 Lbs/Gal | |
| NONEXEMPT VOC'S (CVOC): | 61.0 Vol. % / 519.8 g/L / 4.330 Lbs/Gal | |
| HAZARDOUS AIR POLLUTANTS (HAPS) | 15.7 Wt. % /130.5 g/L / 1.087 Lbs/Gal | |
| VAPOR PRESSURE (mm of Hg) @ 20 C | 106.5 | |
| NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C) | 8.4 | |
| VAPOR DENSITY (air = 1) | 2.8 | |
| WATER ABSORPTION: | Appreciable | |
| REFRACTIVE INDEX: | 1.399 | |
| MIXED ANILINE POINT (Acid Insol) | 33 C/ 93 F | |
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SECTION
10. REACTIVITY DATA
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| STABILITY | ||
| Stable | ||
| CONDITIONS TO AVOID | ||
| Isolate from oxidizers, heat, sparks, electric equipment, & open flame. | ||
| MATERIALS TO AVOID | ||
| Isolate from strong oxidizers such as permanganates, chromates, & peroxides. | ||
| HAZARDOUS DECOMPOSITION PRODUCTS | ||
| Carbon Monoxide, Carbon Dioxide from burning. | ||
| HAZARDOUS POLYMERIZATION | ||
| Will not occur. | ||
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NOTICE
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| The
supplier disclaims all expressed or implied warranties of merchantability
or fitness for a specific use, with respect to the product or the information
provided herein, except for conformation to contracted specifications. All information appearing herein is based upon
data obtained from manufacturers and / or recognized technical sources.
While the information is believed to be accurate, we make no representations
as to its accuracy or sufficiency. Conditions
of use are beyond our control, and therefore users are responsible for
verifying the data under their own operating conditions to determine whether
the product is suitable for their particular purposes and they assume
all risks of their use, handling, and disposal of the product. Users also
assume all risks in regards to the publication or use of, or reliance
upon, information contained herein. This
information relates only to the product designated herein, and does not
related to its use in combination with any other material or process. |
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